Exam-Style Mock Test | Class 11 Chemistry: Hydrocarbons
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Hydrocarbons Mock Test – Class 11 Chemistry

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Hydrocarbons – Progressive Test

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1. In naming a branched alkane, the parent chain is selected as the

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2. Alkynes, like alkanes and alkenes, are generally poorly soluble in water because they are

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3. The reagent pair used for hydration of an alkene to an alcohol is commonly represented as

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4. A branched alkyl halide undergoes elimination with alcoholic . The major alkene is usually the one that is

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5. In electrophilic aromatic substitution of benzene, the step that restores aromaticity is usually

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6. A reaction comparison is shown below.

Reaction route Typical carbon-count effect
P. reduction carbon skeleton retained
Q. Wurtz reaction with one alkyl halide alkyl group count effectively doubles
R. Soda-lime decarboxylation alkane has one carbon fewer than the carboxylate salt

The comparison supports the conclusion that

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7. In a combustion analysis, of hydrocarbon gives and . decolourises bromine water and consumes in complete hydrogenation. The most suitable formula and class are

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8. A benzene ring already carrying one group undergoes further substitution. The group is generally

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9. But--yne and but--yne only are present in a mixture. The mixture consumes of on complete addition. A separate equal sample gives of silver acetylide derivative with ammoniacal silver nitrate. The moles of but--yne are

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10. In the same relative-rate comparison of toluene, benzene, and nitrobenzene, the lowest bar should correspond to

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11. Methane reacts with chlorine in the presence of light. The first monochlorinated product is

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12. A table lists alkenes and their ability to show geometrical isomerism.

Row Alkene Claim
P does not show cis-trans isomerism
Q can show cis-trans isomerism
R does not show cis-trans isomerism
S cannot show cis-trans isomerism because it has a double bond

The row that needs correction is

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13. Ozonolysis of , followed by reductive work-up, gives

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14. A set of names and structural meanings is shown below.

Row Name fragment Meaning
P -carbon parent chain
Q carbon-carbon triple bond
R open-chain structure
S substituent

The row needing correction is

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15. The suitable IUPAC name for is

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16. The general Wurtz reaction for a single alkyl halide is best represented as

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17. A statement says, “Alkynes and alkenes both undergo addition reactions, so one mole of reagent always completely saturates them.” The best correction is that

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18. A chain compound written as is named

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19. In and , the main difference is the

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20. The decolourisation of dilute alkaline by an alkene is used as a test for

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21. Complete hydrogenation converts of into . The hydrogen gas is supplied from a cylinder at . The minimum volume of required is

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22. A benzene ring carrying a group is commonly named

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23. The suitable name for is

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24. The pair and has

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25. Ethyne reacts with excess bromine. The final saturated product is best represented as

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26. In the classification map below, the missing entry at is most suitable for which hydrocarbon type?

Hydrocarbon feature Broad class
Open-chain, only single bonds Alkane
Open-chain, at least one
Open-chain, at least one Alkyne

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27. During complete hydrogenation, of an open-chain hydrocarbon consumes of . The hydrogenated product on complete combustion gives of . The formula of is

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28. A table of alkene names and structures is shown below.

Row Name Structure
P ethene
Q propene
R but--ene
S but--ene

The row that needs correction is

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29. A reaction record for alkane halogenation is shown below.

Row Condition or reagent Interpretation
P with light radical substitution may occur
Q with heat radical bromination may occur
R alkane plus halogen substitution occurs
S without radical-forming condition reaction is much less favoured

The row that needs correction is

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30. The table gives four descriptions. Select the row that gives the best broad classification.

Row Description Broad class
P Open-chain hydrocarbon Aliphatic
Q Non-aromatic ring hydrocarbon Alicyclic
R Benzene-ring hydrocarbon Aromatic
S Hydrocarbon containing oxygen Saturated

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31. Assertion: In ordinary addition of to propene, is the major product.
Reason: The intermediate formed by adding to the terminal carbon is a more stable secondary carbocation.

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32. The energy profile for electrophilic addition to an unsymmetrical alkene is often controlled by the relative stability of possible carbocation intermediates. The more favoured path generally forms

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33. For addition of to ethene, of ethene reacts completely with excess . The amount of bromoethane formed is

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34. A comparison of propene addition products is given below.

Reagent condition Major product
P. , no peroxide
Q. , peroxide
R.
S. becomes more unsaturated

The entry that needs correction is

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35. Addition of to propene in the absence of peroxide mainly gives

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36. A hydrocarbon is named from a parent chain of carbon atoms with only single bonds. The root and suffix combination should be

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37. Different spatial arrangements of ethane obtained by rotation around its single bond are called

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38. The Wurtz reaction uses alkyl halides with sodium metal in

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39. Benzene usually prefers substitution over addition because substitution

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40. For straight-chain alkynes in a homologous series, the boiling point generally increases as the carbon number increases mainly because

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41. Alkenes are hydrocarbons that contain at least one

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42. A table compares physical-property statements for alkenes.

Row Statement
P Alkenes are generally non-polar hydrocarbons.
Q Alkenes are usually insoluble in water.
R Boiling point generally increases with molecular size in a homologous series.
S All alkenes are highly soluble in water because of the bond.

The row that needs correction is

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43. A hydrocarbon sample decolourises bromine water and also decolourises cold dilute alkaline . The most likely conclusion is that the sample contains

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44. A hydrocarbon test table is shown below.

Row Observation Most suitable interpretation
P Bromine water decolourised quickly possible or
Q Ammoniacal gives precipitate terminal alkyne likely
R Cold alkaline decolourised unsaturation may be present
S Bromine water decolourised compound must be only ethene

The row that needs correction is

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45. For Kolbe electrolysis of , the main symmetrical alkane product contains how many carbon atoms?

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46. A cracking record states:

Assuming only one other hydrocarbon product is formed, the formula of is

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47. The dihedral angle between a front bond and the nearest rear bond is in an eclipsed ethane conformation. In the nearest staggered conformation, it becomes

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48. In naming an alkene, the parent chain must be chosen so that it

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49. The catalyst commonly used in Friedel-Crafts alkylation is

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50. Assertion: Wurtz reaction is especially useful for preparing symmetrical alkanes.
Reason: Two identical alkyl halide molecules couple to give one main product.

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