Solutions Mock Test – Class 12 Chemistry
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Solutions Mock Test – Class 12 Chemistry

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Solutions – Progressive Test

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1. A binary ideal solution has , , and . The contribution of to the total vapour pressure is:

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2. A non-volatile nonelectrolyte solution has and . If , the value of for the same solvent is:

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3. A solution shows and . This observation most directly suggests:

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4. A student writes after starting from Henry's law . The correction is:

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5. In reverse osmosis used for desalination, the semipermeable membrane mainly allows:

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6. A density-linked concentration conversion is most likely required when:

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7. A table for molar-mass determination from boiling point elevation is given below.

Row Quantity Correct use
P
Q Constant of the solvent
R Mass of solvent
S Mass of total solution

The row that needs correction is:

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8. A student calculates relative lowering as . The correction is to divide by:

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9. Complete dissociation occurs in a aqueous solution. At , using , its osmotic pressure is:

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10. A statement says, “The vapour pressure of a solution is discussed without fixing temperature because temperature has no effect on vapour pressure.” The best correction is:

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11. Assertion: An ideal solution obeys Raoult's law over the entire composition range.
Reason: In an ideal solution, unlike interactions are very different from like interactions.

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12. A data table for aqueous solutions at the same temperature is shown below.

Solution Formal concentration Solute behaviour
P Glucose, no dissociation
Q , complete dissociation
R , complete dissociation
S Dimerizing solute with

The decreasing order of osmotic pressure is:

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13. A true solution is best described as a mixture in which the components are:

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14. Two mixtures remain stable without visible settling. When a narrow beam of light is passed through them, the path of the beam is invisible in Mixture P but clearly visible in Mixture Q. The most suitable classification is:

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15. In the notation of a binary solution, components and are used. The safest interpretation of and at this stage is that they are:

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16. A report compares four concentration terms for a dissolved solid.

Term Best use or basis
P. Mass of solute per mass units of solution
Q. Mass of solute per solution
R. Very dilute concentration scaled by
S. Moles of solute per litre of solution

The mismatched entry is:

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17. A saline solution is separated from pure water by a semipermeable membrane. A pressure larger than its osmotic pressure is applied on the saline side. The expected result is:

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18. A weak electrolyte dissociates as . If the degree of dissociation is , the van't Hoff factor is:

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19. A table compares ideal-solution checks.

Row Check Ideal-solution expectation
P Raoult's law Obeyed over entire composition range
Q
R
S interactions Much weaker than and

The row that does not match ideal behaviour is:

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20. Trimer formation gives . The degree of association is:

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21. The situation-relation pairing that is mismatched is:

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22. Simple fractional distillation cannot separate an azeotropic mixture at its azeotropic composition because:

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23. A table gives four situations.

Row Situation Expected
P Nonelectrolyte, no association
Q Complete dimerisation
R Complete dissociation into ions
S Complete dimerisation

The row that needs correction is:

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24. A non-volatile solute dimerizes in a solvent. If its normal calculated freezing point depression is , the observed freezing point depression is:

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25. A student is comparing two colligative-property questions. Case gives , , solute mass, and solvent mass. Case gives , , , and solute mass. The correct pairing is:

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26. Assertion: Soda water is classified as a liquid solution.
Reason: The phase of a solution is generally determined by the solvent, and water is the solvent in soda water.

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27. A laboratory note says . The most suitable interpretation is:

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28. For a very dilute aqueous solution, by mass most nearly represents:

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29. The molecular reason for non-ideal behaviour is best stated as:

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30. For an ideal solution of two volatile liquids and , Raoult's law for component is:

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31. Assertion: Molarity can change when the temperature of a solution changes.
Reason: Molarity uses volume of solution in its denominator, and liquid volume can expand or contract with temperature.

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32. A sample contains glucose dissolved in water to make solution. Given , the concentration term that can be calculated directly from the given data without density is:

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33. The unit of in the Henry's law relation is:

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34. A solute has normal molar mass , but its apparent molar mass from a colligative property is . The van't Hoff factor is:

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35. A gas chemically reacts with water after dissolving. A simple Henry's law calculation may fail because:

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36. A hot saturated solution of is cooled carefully without disturbance and remains clear, even though its concentration is higher than the normal solubility at the lower temperature. The solution is:

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37. A learner calculates mass percentage by using . The main error is:

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38. The unit of in is:

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39. A gas is dissolved in a liquid at constant temperature. Increasing the pressure of the gas above the liquid generally:

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40. A table for degree of dissociation is shown below.

Row Dissociation For complete dissociation,
P
Q
R
S

The row that needs correction is:

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41. Assuming Raoult's law applies, a pure solvent has vapour pressure . After adding a non-volatile solute, the solute mole fraction is . The lowering of vapour pressure is:

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42. Consider the following statements about true solutions.
Statement I: A true solution has uniform composition throughout.
Statement II: A true solution may be solid, liquid, or gas.
Statement III: A true solution must always be colourless.

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43. Henry's law applies to a gas at a fixed temperature with . If the mole fraction of the gas in solution is , its partial pressure is:

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44. The association summary below contains one faulty row.

Row Association type Complete-association Particle-count effect
P dimerisation Decreases
Q trimerisation Decreases
R tetramerisation Decreases
S dimerisation Increases

The row that needs correction is:

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45. The association result that is not consistent with the stated process is:

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46. A pure solvent freezes at . A solution has . The freezing point of the solution is:

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47. A substance has molar mass . The amount of substance in of it is:

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48. A solute shows in a solvent. If the normal calculated osmotic pressure is , the observed osmotic pressure is:

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49. For a dilute solution containing grams of a nonelectrolyte solute in volume , osmotic pressure is measured at temperature . The molar mass is given by:

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50. The relation between van't Hoff factor, normal molar mass, and abnormal molar mass is:

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